Kinetics of no decomposition over Cu/ZSM-5 catalyst |
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Authors: | V. Toma i , Z. Gomzi S. Zrn evi |
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Affiliation: | (1) Faculty of Chemical Engineering and Technology, Department of Reaction Engineering and Catalysis, University of Zagreb, Croatia |
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Abstract: | The kinetics of catalytic decomposition of NO over Cu/ZSM-5 catalyst has been studied in an integral flow reactor at atmospheric pressure. Kinetic analysis is based on the assumption that the surface reaction represents the rate-determining step. On the basis of theoretical considerations of different interactions between reactants and catalyst, and experimental evidences, three different mechanistic kinetic models were chosen. Also a power-law model was tested. The best agreement has been achieved with the model |
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Keywords: | Catalytic decomposition of NO kinetics and mechanism Cu/ZSM-5 catalyst |
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