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Kinetics of no decomposition over Cu/ZSM-5 catalyst
Authors:V Toma&#;i&#;  Z Gomzi and S Zrn&#;evi&#;
Institution:(1) Faculty of Chemical Engineering and Technology, Department of Reaction Engineering and Catalysis, University of Zagreb, Croatia
Abstract:The kinetics of catalytic decomposition of NO over Cu/ZSM-5 catalyst has been studied in an integral flow reactor at atmospheric pressure. Kinetic analysis is based on the assumption that the surface reaction represents the rate-determining step. On the basis of theoretical considerations of different interactions between reactants and catalyst, and experimental evidences, three different mechanistic kinetic models were chosen. Also a power-law model was tested. The best agreement has been achieved with the model

$$r_S  = \frac{{k \cdot C_{NO} ^2 }}{{\left( {1 + \sqrt {K_D ^1  \cdot C_{O_2 } } } \right)^2 }}$$
Keywords:Catalytic decomposition of NO  kinetics and mechanism  Cu/ZSM-5 catalyst
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