FTIR spectroscopic studies of the matrix photoionization and photolysis products of methylene halides |
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Authors: | Benuel J. Kelsall Lester Andrews |
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Affiliation: | Department of Chemistry, University of Virginia, Charlottesville, Virginia 22901 USA |
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Abstract: | Matrix photoionization of methylene bromide produced absorptions at 1019, 897, and 788 cm?1 identified previously as CBr2+, CHBr2+, and CHBr2. High-resolution FTIR spectra revealed overlapping 1/2/1 triplets for natural bromine isotopes with individual linewidths near 0.2 cm?1. New absorptions at 3121, 2897, and 1345 cm?1 are assigned to the (CH2Br+)Br cation complex which yields CHBr2+ on photolysis. A substantially increased yield of the CHCl2+ species made possible observation of the CH stretching mode at 3033 cm?1 and the symmetric CCl2 stretching mode at 845 cm?1 along with the previously observed stronger 1291- and 1044-cm?1 fundamentals. The high resolution and enhanced signal-to-noise capability of the FTIR are clearly demonstrated in this investigation. |
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