The 404.5-nm system of the ReO molecule |
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Authors: | Walter J. Balfour Ram S. Ram |
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Affiliation: | Department of Chemistry, University of Victoria, Victoria, B. C., V8W 2Y2, Canada |
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Abstract: | Observations on the emission spectrum of ReO in the region 375–870 nm are reported. Five bands of a system with (0, 0) band at 404.5 nm have been rotationally analyzed and the principal results for 187ReO are (in cm?1) ν0 = 24 709.90, B′e = 0.3819, B″e = 0.4252, ω′e = 874.82, and . Data on the minor isotopic species 185ReO are also reported. It is suggested that broad rotational profiles found in bands near 842 nm may be due to nuclear hyperfine structure. |
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