Improved rovibrational constants and frequency tables for the normal laser bands of 12C16O2 |
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Authors: | FRussell Petersen Earl C Beaty CR Pollock |
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Institution: | Time and Frequency Division, National Bureau of Standards, Boulder, Colorado 80303 USA |
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Abstract: | New frequency difference measurements between Doppler-free stabilized laser lines in the 9.4- and 10.4-μm bands of 12C16O2, including high-J and across-the-band-center measurements, have made significant improvements in the rovibrational constants. The absolute frequencies were referred to the methane stabilized 3.39-μm HeNe laser. Frequency tables generated from these constants have absolute uncertainties of less than two parts in 1010 and are about a factor of 10 better than older tables. In addition, the laser lines PI(50) in 13C16O2 and RII(26) in 13C18O2, which were used as reference lines in recent visible laser frequency measurements, were also measured to about the same accuracy. |
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