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Highly selective epoxidation of styrene using a transition metal-aluminium(III) complex containing the [MeAl(2-py)3]- anion (2-py = 2-pyridyl) |
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| Authors: | Alvarez Carmen Soria García Felipe Humphrey Simon M Hopkins Alexander D Kowenicki Richard A McPartlin Mary Layfield Richard A Raja Robert Rogers Michael C Woods Anthony D Wright Dominic S |
| Institution: | University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, UK CB2 1EW. |
| Abstract: | The reactions of MeAl(2-py)3Li.thf] (1) with FeCl2 or Cp2Mn in toluene-thf give simple access to the Group 13-transition metal heterometallic complexes {MeAl(2-py)3}2M]M = Fe (2), Mn (3)]; complex has been shown to be a highly selective styrene epoxidation catalyst in air. |
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