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Selective Acetylation of Alcohols and Amines with Ethyl Acetate in the Presence of H6[PMo9V3O40] as the Catalyst
Authors:Majid M. Heravi  Khadijeh Bakhtiari  Negar M. Javadi  Hossein A. Oskooie  Fatemeh F. Bamoharram
Affiliation:(1) Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran, Iran;(2) Department of Chemistry, Azad University of Mashhad, Mashhad, Iran
Abstract:Summary. Acetylation of various alcohols and benzyl amine was tested in the presence of H6[PMo9V3O40], a mixed addenda heteropolyacid, in ethyl acetate under reflux condition. Phenols and anilines are not affected under the reaction conditions. Selective transestrification of alcohols can be achieved in the presence of phenol and aniline derivatives using this method.
Keywords:. Acetylation   Transestrification   Alcohols   Mixed addenda heteropolyacids   Ethyl acetate.
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