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Cohesively Enhanced Conductivity and Adhesion of Flexible Silver Nanowire Networks by Biocompatible Polymer Sol–Gel Transition
Authors:Yunxia Jin  Lu Li  Yuanrong Cheng  Lingqiang Kong  Qibing Pei  Fei Xiao
Institution:1. Department of Materials Science, Fudan University, Shanghai, P.R. China;2. Department of Materials Sciences and Engineering, California NanoSystems Institute, Henry Samuli School of Engineering and Applied Science, University of California, Los Angeles, CA, USA
Abstract:Silver nanowire (AgNW) networks are a promising candidate to replace indium tin oxide (ITO) as transparent conductors. In this paper, a novel transparent composite conductor composed of AgNW/biocompatible alginate gel on a flexible polyethylene terephthalate (PET) substrate, with synchronously enhanced adhesion and reduced resistivity, is prepared without high‐temperature annealing. The sheet resistance of the flexible AgNW/PET film reduces from 300 to 50.3 Ohm sq?1 at transmittance of 94%. The optical and electrical performance is superior to that obtained from the flexible ITO film on PET. Meanwhile, the sheet resistance does not show great change after tape test, suggesting a good adhesion of AgNW to the polymer substrate. Moreover, the AgNW composite film shows a good stability to resist long‐term storage, solvent damage, and ultrasonication. Finally, polymer solar cells employing the composite AgNW film as the electrode are realized, displaying an efficiency of 2.44%.
Keywords:alginate gel  polymer adhesive  silver nanowires  transparent conductor
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