Novel aziridination of olefins: direct synthesis from sulfonamides using t-BuOI |
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| Authors: | Minakata Satoshi Morino Yoshinobu Oderaotoshi Yoji Komatsu Mitsuo |
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| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan. minakata@chem.eng.osaka-u.ac.jp |
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| Abstract: | tert-Butyl hypoiodite (t-BuOI) was found to be a powerful reagent for synthesis of aziridines from olefins and sulfonamides. The aziridination of olefins was achieved by using sulfonamides with t-BuOI. Our preliminary findings represent the example of metal-free aziridination of olefins with readily accessible sulfonamides as a nitrogen source. |
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