| PPh3修饰介孔泡沫材料负载的Rh催化剂用于固定床氢甲酰化反应 |
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| 引用本文： | 严丽,丁云杰,朱何俊,尹红梅,焦桂平,赵东元,林励吾.PPh3修饰介孔泡沫材料负载的Rh催化剂用于固定床氢甲酰化反应[J].催化学报,2006,27(1):1-3. |
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| 作者姓名： | 严丽 丁云杰 朱何俊 尹红梅 焦桂平 赵东元 林励吾 |
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| 作者单位： | 中国科学院大连化学物理研究所,辽宁,大连,116023;中国科学院研究生院,北京,100049;中国科学院大连化学物理研究所,辽宁,大连,116023;复旦大学化学系,上海,200433 |
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| 基金项目： | 国家自然科学基金资助项目(20073046)，国家重点基础研究发展计划(973计划)资助项目(G2003CB615803). |
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| 摘 要： | 介孔泡沫材料（MCF）是一种孔径有序，孔结构无序，稳定性高的新型纯硅基分子筛。MCF的开放式孔结构和可调变孔径使其适合于做催化剂的载体. 我们采用MCF为载体制备了PPh3-Rh/MCF催化剂，并应用于固定床中的丙烯氢甲酰化反应中（丙烯转化率21.6%，丁醛的时空收率160.6 mol醛/mol Rh·小时，正异比10.4）.PPh3-Rh/MCF催化剂的稳定性远远高于HRh(CO)(PPh3)3/MCF催化剂.
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| 关 键 词： | 三苯基膦 铑 介孔泡沫材料 负载型催化剂 丙烯 氢甲酰化 |
| 文章编号： | 0253-9837（2006）01-0001-03 |
| 收稿时间： | 09 20 2005 12:00AM |
| 修稿时间： | 2005年9月20日 |
Continuous Fixed-Bed Gas-Phase Hydroformylation over PPh3-Modified Mesostructured Cellular Foam-Supported Rh Catalyst |
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| YAN Li,DING Yunjie,ZHU Hejun,YIN Hongmei,JIAO Guiping,ZHAO Dongyuan,LIN Liwu.Continuous Fixed-Bed Gas-Phase Hydroformylation over PPh3-Modified Mesostructured Cellular Foam-Supported Rh Catalyst[J].Chinese Journal of Catalysis,2006,27(1):1-3. |
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| Authors: | YAN Li DING Yunjie ZHU Hejun YIN Hongmei JIAO Guiping ZHAO Dongyuan LIN Liwu |
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| Institution: | 1.Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China ; 2. Graduate School of The Chinese Academy of Sciences, Beijing 100049, China ; 3.Department of Chemistry, Fudan University, Shanghai 200433, China |
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| Abstract: | Siliceous mesostructured cellular foams (MCFs) are a new class of three-dimensional hydrothermally robust materials with ultralarge mesopores. The open system of large pores and the controllable pore size give MCFs unique advantages as catalyst supports. In this paper, MCFs were employed as supports in developing the PPh_3-Rh/MCF catalyst for propylene hydroformylation in a fixed-bed reactor. The PPh_3-Rh/MCF catalyst shows high activity (propylene conversion of 21.6% and butyraldehyde TOF of 160.6 h -1), high selectivity (n-butyraldehyde/i-butyraldehyde=10.4), and excellent stability under mild conditions of p=1.0 MPa, T=393 K, and SV= 2?000 h -1. |
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| Keywords: | triphenyl phosphine rhodium mesostructured cellular foam supported catalyst propylene hydroformylation |
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