| 含磷钼酸及2,2’-联吡啶-3,3’-二羧酸配体的铜配位聚合物的合成、晶体结构与电化学性质 |
| |
| 引用本文： | 王志花,王鑫鹏,赵胜能,王琴,孟祥高,靳素荣.含磷钼酸及2,2’-联吡啶-3,3’-二羧酸配体的铜配位聚合物的合成、晶体结构与电化学性质[J].无机化学学报,2013,29(9):1877-1881. |
| |
| 作者姓名： | 王志花 王鑫鹏 赵胜能 王琴 孟祥高 靳素荣 |
| |
| 作者单位： | 1. 武汉理工大学理学院化学系,武汉,430070
2. 华中师范大学化学学院,武汉,430072 |
| |
| 基金项目： | 中央高校基本科研业务费专项资金(批准号:2012-Ia-042)资助项目。 |
| |
| 摘 要： | 在水热条件下合成了一个新的化合物{Cu4(PMo12O40)(H2O)5(H2bpdc)(Hbpdc)(bpdc)2].6H2O}n(H2bpdc=2,2′-联吡啶-3,3′-二羧酸),并用元素分析、IR、TG和X-射线衍射等手段进行了表征。结果表明本化合物的晶体结构中,最小不对称单元包含1个Cu4(H2O)5(H2bpdc)(Hbpdc)(bpdc)2]3+阳离子,1个PMo12O40]3-阴离子和6个结晶水分子。Cu(Ⅱ)与相邻PMo12O40]3-的桥氧原子配位,形成一维链状结构。电化学研究表明,化合物存在三步氧化还原过程。
|
| 关 键 词： | 多金属氧酸盐 铜配位聚合物 水热合成 晶体结构 |
| 收稿时间： | 2012/7/21 0:00:00 |
| 修稿时间： | 5/4/2013 12:00:00 AM |
Synthesis, Crystal Structure and Electrochemical Property of a Copper Coordination Polymer Containing Molybdophosphate and 2,2'-Bipyridine-3,3'-dicarboxylic Acid Ligands |
| |
| WANG Zhi-Hu,WANG Xin-Peng,ZHAO Sheng-Neng,WANG Qin,MENG Xiang-Gao and JIN Su-Rong.Synthesis, Crystal Structure and Electrochemical Property of a Copper Coordination Polymer Containing Molybdophosphate and 2,2'-Bipyridine-3,3'-dicarboxylic Acid Ligands[J].Chinese Journal of Inorganic Chemistry,2013,29(9):1877-1881. |
| |
| Authors: | WANG Zhi-Hu WANG Xin-Peng ZHAO Sheng-Neng WANG Qin MENG Xiang-Gao and JIN Su-Rong |
| |
| Institution: | School of Science, Wuhan University of Technology, Wuhan 430070, China;School of Science, Wuhan University of Technology, Wuhan 430070, China;School of Science, Wuhan University of Technology, Wuhan 430070, China;School of Science, Wuhan University of Technology, Wuhan 430070, China;College of Chemistry, Central China Normal University, Wuhan 430072, China;School of Science, Wuhan University of Technology, Wuhan 430070, China |
| |
| Abstract: | A complex {Cu4(PMo12O40)(H2O)5(H2bpdc)(Hbpdc)(bpdc)2]·6H2O}n was synthesized under hydrothermal condition using H3PMo12O40·xH2O,H2bpdc, CuSO4·5H2O as raw materials and characterized by elemental analysis, IR,TG and single-crystal X-ray diffraction. The title compound consists of polyoxoanionPMo12O40]3-, cationsCu4(H2O)5(H2bpdc)(Hbpdc)(bpdc)2]3 and lattice water molecules. The structure refinement indicates that the title compound forms a one-dimensional chain from the polyanions andCu4(H2O)5(H2bpdc)(Hbpdc)(bpdc)2]3 through O bridge. The cyclic voltammogram indicates that three couples redox waves are observed on the compound modified carbon paste electrode. CCDC: 748899. |
| |
| Keywords: | polyoxometalate copper coordination polymer hydrothermal synthesis crystal structure |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
