Aminoborylation/Suzuki-Miyaura tandem cross coupling of aryl iodides as efficient and selective synthesis of unsymmetrical biaryls |
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| Authors: | Marciasini Ludovic Richy Nicolas Vaultier Michel Pucheault Mathieu |
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| Institution: | Institut des Sciences Moléculaires, UMR CNRS 5255, Université Bordeaux 1, 351 Cours de la Libération, F-33405 Talence Cedex, France. |
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| Abstract: | Sequential borylation of a first aryl iodide using a dialkylaminoborane followed by a Suzuki-Miyaura cross coupling of second aryl iodide ended up with an efficient, selective and practical synthesis of unsymmetrical biaryls. This tandem coupling shows a wide range of applicability. |
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