Kinetics of reactions of derivatives of bischloromethylphosphinic acid with amines |
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| Authors: | M K Il'ina I M Shermergorn |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry of the Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions The authors have made a kinetic study of nucleophilic replacement of chlorine by an amino group in derivatives of bischloromethylphosphinic acid. The process takes place by an SN1-mechanism in the case of weak nucleophilic reagents (the aniline type) and by an Sn2-mechanism in the case of strong nucleophilic reagents (benzylamine type).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 175–177, January, 1969. |
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