Selective transformation of organoboranes to grignard reagents by using pentane-1,5-di(magnesium bromide). Syntheses of the pheromones of southern armyworm moth and Douglas fir tussock moth |
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Authors: | Kaoru Kondo Shun-Ichi Murahashi |
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Institution: | Department of Chemistry, Faculty of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka, Japan, 560 |
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Abstract: | The selective transformation of trialkylboranes or B-alkyl-9-borabicyclo3.3.1]-nonanes to alkylmagnesium bromides was accomplished upon treatment with pentane-1,5-di(magnesium bromide) () in benzene. |
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