A short synthesis of ishwarone |
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| Authors: | Robert M. Cory Dominic M.T. Chan Fred R. McLaren Mary H. Rasmussen Richard M. Renneboog |
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| Affiliation: | Department of Chemistry, University of Western Ontario, London, Ontario, N6A 5B7, Canada |
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| Abstract: | 2,3,4-Trimethyl-2-cyclohexenone can be converted to the corresponding isoprene Diels-Alder adduct by a sequence initiated by conjugate addition of lithium bis(3-methyl-3-butenyl)cuprate; the sesquiterpenoid ishwarone has been synthesized in two steps from the resulting octalone. |
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