Novel rearrangement of prop-2-ynyl N-Oxides to hydroxylamine O-allenyl ethers: mechanistic studies |
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| Authors: | J.Cymerman Craig Nnochiri N. Ekwuribe Larry D. Gruenke |
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| Affiliation: | Department of Pharmaceutical Chemistry, School of Pharmacy University of California, San Francisco, California, 94143, U.S.A. |
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| Abstract: | The novel thermolytic rearrangement of prop-2-ynyl N-Oxides to hydroxylamine O-allenyl ethers has been examined by deuterium labeling. Product analysis by gc-eims and by cims has shown the reaction to proceed by a concerted cyclic transition state. |
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