Isoprenic thiovinylcarbenes. 2. Intermolecular reactions with olefins,dienes and acetylenes. Direct access to chrysanthemic esters. |
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Authors: | M Franck-Neumann JJ Lohmann |
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Abstract: | The isoprenic thiovinylcarbene formed by photolysis of gem-dimethyl-5-ethylthiopyrazolenine shows a surprisingly good intermolecular reactivity toward electrophilic olefins and acetylenes. A direct access to chrysanthemic esters is thus provided. |
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