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Isoprenic thiovinylcarbenes. 2. Intermolecular reactions with olefins,dienes and acetylenes. Direct access to chrysanthemic esters.
Authors:M Franck-Neumann  JJ Lohmann
Abstract:The isoprenic thiovinylcarbene formed by photolysis of gem-dimethyl-5-ethylthiopyrazolenine shows a surprisingly good intermolecular reactivity toward electrophilic olefins and acetylenes. A direct access to chrysanthemic esters is thus provided.
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