Electroreductive crossed hydrocoupling of aromatic ketones with enol acetates |
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| Authors: | Tatsuya Shono Hiroshi Ohmizu Souta Kawakami |
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| Affiliation: | Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Sakyo, Kyoto 606, Japan |
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| Abstract: | Cathodic reduction of aromatic ketones in the presence of enol acetates afforded crossed hydrocoupling products, that is, unsymmetrical pinacols, in which the new carbon-carbon bond formation took place between the carbonyl carbon of aromatic ketones and the carbon bearing acetoxyl group in enol acetates. |
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