A new method for fluorination of sterols |
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Authors: | Shlomo Rozen Yonah Faust Hadassah Ben-Yakov |
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Institution: | Chemistry Department, Tel-Avid University, Tel-Aviv, Israel |
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Abstract: | Diethylaminosulfurtrifluoride (DAST) is a good fluorinating reagent for sterols. The fluorinating reactions proceed through SN2 mechanism, while reactions through free carbonium ion are responsible for rearrangements and eliminations. |
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