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The unexpected thermal instability of 3,4-tetramethylene-1,2-dioxetane as compared to that of cis-3,4-diethyl-1,2-dioxetane.
Authors:AL Baumstark  CE Wilson
Institution:Department of Chemistry, Georgia State University, Atlanta, Georgia 30303 U.S.A.
Abstract:3,4-Tetramethylene- and cis-3,4-diethyl-1,2-dioxetane (1 and 2) were prepared and characterized (for 1 - Ea = 22.5 kcal/mole, log A = 12.8; for 2 - Ea = 24.5 kcal/mole, log A = 13.1).
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