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A very crowded molecule: formation of bis(2,4,6-tri-t-butylphenyl)phosphinic chloride
Authors:Masaaki Yoshifuji  auIchiro Shima  Naoki Inamoto
Institution:Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo Tokyo 113, Japan
Abstract:Reaction of 2,4,6-ri-t-butylphenyllithium with phosphoryl trichloride gave a very crowded compound, bis(2,4,6-tri-t-butylphenyl)phosphinic chloride (1), and 2,4,6-tri-t-butylchlorobenzene (3), while the reaction with thiophosphoryl trichloride afforded 3.
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