A very crowded molecule: formation of bis(2,4,6-tri-t-butylphenyl)phosphinic chloride |
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Authors: | Masaaki Yoshifuji auIchiro Shima Naoki Inamoto |
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Institution: | Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo Tokyo 113, Japan |
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Abstract: | Reaction of 2,4,6-ri-t-butylphenyllithium with phosphoryl trichloride gave a very crowded compound, bis(2,4,6-tri-t-butylphenyl)phosphinic chloride (), and 2,4,6-tri-t-butylchlorobenzene (), while the reaction with thiophosphoryl trichloride afforded . |
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