Acylation of 4-substituted 6-hydroperoxy-2,6-di--butyl-2,4-cyclohexadienones |
| |
| Authors: | A Nishinaga K Nakamura T Shimizu T Matsuura |
| |
| Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Kyoto, Japan |
| |
| Abstract: | Acylation of 4-aryl-2,6-di--butyl- and 2,4,6-tri--butyl- 6-hydroperoxy-2,4-cyclohexadienones gave unexpected products, 4-acyloxy-5,6-epoxy-2-cyclohexenones and 2-acyloxy-5,6-epoxy-3-cyclohexenones. The reaction involves a rapid homolysis of the peroxy bond of peroxy esters transiently formed in the pre-existing slow step. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
