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Radical ions in photochemistry 10. The photosensitized (electron-transfer) isomerization of 1,2-diphenylcyclopropanes.
Authors:Po Cheong Wong  Donald R. Arnold
Affiliation:The Photochemistry Unit, Department of Chemistry University of Western Ontario, London, Ontario, Canada N6A 5B7
Abstract:The photoisomerization of the 1,2-diphenylcyclopropanes in polar solvent sensitized by 1-cyano- and 1,4-dicyanonaphthalene proceeds via an electron-transfer mechanism. An analysis of photo-CIDNP results provide details regarding the intermediates.
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