Asymmetric epoxidation of hydrocarbon olefins by <span class="math"><math><mtext>tert</mtext></math></span>-butyl hydroperoxide with molybdenum(VI) catalysts in the presence of optically active diols. Application to the asymmetric synthesis of (3S)-2,3-oxidosqualene期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Asymmetric epoxidation of hydrocarbon olefins by $tert$ -butyl hydroperoxide with molybdenum(VI) catalysts in the presence of optically active diols. Application to the asymmetric synthesis of (3S)-2,3-oxidosqualene

Authors:	Kazuhide Tani Masayoshi Hanafusa Sei Otsuka

Institution:	Department of Chemistry, Faculty of Engineering Science, Osaka University Toyonaka, Osaka, Japan 560

Abstract:	Catalytic enantioselective epoxidation of prochiral olefins without functional groups was achieved by $tert$ -BuOOH using Mo(O)₂(acac)₂-optically active diols as catalysts.

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