Interaction in the system Bi(NO3)3-K3HCit-(H2O + glycerol) |
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| Authors: | T B Kuvshinova V M Skorikov V D Volodin L I Demina |
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| Institution: | 1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia
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| Abstract: | The interaction in the system Bi(NO3)3-K3HCit-(H2O + glycerol) was studied by chemical analysis and pH titration over a wide range of ratios between the initial components. Solid phases of the compositions Bi(OH)3?3x HCit x · nH2O and KBiCit · H2O were isolated and investigated by X-ray powder diffraction and differential thermal analyses and IR spectroscopy. The effect of the chemical nature of the alkali metal on the solubility in the system under consideration was demonstrated. |
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