| 溶剂驱动四甲基六元瓜环桥联聚丙烯酸的苯酚派生物对杀菌剂的吸附和解析 |
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| 引用本文： | 陈鹏,高瑞晗,肖勃,祝黔江,陶朱. 溶剂驱动四甲基六元瓜环桥联聚丙烯酸的苯酚派生物对杀菌剂的吸附和解析[J]. 功能高分子学报, 2017, 30(2). DOI: 10.14133/j.cnki.1008-9357.2017.02.006 |
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| 作者姓名： | 陈鹏 高瑞晗 肖勃 祝黔江 陶朱 |
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| 作者单位： | 贵州大学,贵州省大环化学及超分子化学重点实验室, 贵阳 550025 |
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| 摘 要： | 根据苏氏一锅法,在过硫酸铵既作为氧化剂又作为引发剂的条件下合成了一系列四甲基六元瓜环桥联聚丙烯酸.研究了丙烯酸浓度、四甲基六元瓜环投入量和过硫酸铵浓度对聚合物形成的影响.四甲基六元瓜环桥联聚丙烯酸可以进一步与苯酚发生酯化反应,生成不溶于水的派生物,因此可用于吸附和解析杀菌剂.
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| 关 键 词： | 四甲基六元瓜环 聚丙烯酸 杀菌剂 |
Solvent-Driven Adsorption on and Desorption from Symmetrical Tetramethylcucurbit[6]uril-Anchored Polyacrylic Acids and Phenol Derivatives of Antiseptics |
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| CHEN Peng,GAO Rui-han,XIAO Bo,ZHU Qian-jiang,TAO Zhu. Solvent-Driven Adsorption on and Desorption from Symmetrical Tetramethylcucurbit[6]uril-Anchored Polyacrylic Acids and Phenol Derivatives of Antiseptics[J]. Journal of Functional Polymers, 2017, 30(2). DOI: 10.14133/j.cnki.1008-9357.2017.02.006 |
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| Authors: | CHEN Peng GAO Rui-han XIAO Bo ZHU Qian-jiang TAO Zhu |
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| Abstract: | A series of tetramethylcucurbit[6]uril-anchored polyacrylic acids (TMeQ[6]-anchored PAAs) were synthesized in the presence of ammonium persulfate (APS) as both an initiator and an oxidant according to Su''s one-pot strategy.The effects of acrylic acid concentration, TMeQ[6] feed mass, and APS concentration on the formation of the polymers were investigated.TMeQ[6]-anchored PAAs can be further esterified with phenol to yield water-insoluble derivatives, thereby permitting the absorption and desorption of antiseptic molecules. |
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| Keywords: | tetramethylcucurbit[6]uril polyacrylic acids antiseptics |
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