Kinetics of thermal conversions of monoterpenic compounds in supercritical lower alcohols |
| |
| Authors: | V. I. Anikeev A. Ermakova A. M. Chibiryaev I. V. Kozhevnikov |
| |
| Affiliation: | 1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
2. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
|
| |
| Abstract: | The most important information concerning thermal conversions of vegetable terpenes (α-pinene, β-pinene, turpentine, and cis-verbenol) in supercritical lower alcohols is systematized. The kinetics of selected reactions is reported and is compared with the kinetics of the same reactions in the gas and liquid phases. Thermodynamic calculations of the phase states and kinetic parameters are presented for a number of multicomponent multiphase systems containing terpenes and lower alcohols. The effect of the supercritical solvent pressure on the rate and selectivity of the selected reactions is reported. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
