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Quantum corrections for lattice gases
Authors:Frank H. Stillinger
Affiliation:(1) Bell Laboratories, Murray Hill, New Jersey
Abstract:Classical lattice gases consisting of structureless particles (with spin) have been quantized by introducing a kinetic energy operator that produces nearest-neighbor hops. Systematic quantum corrections for the partition function and the particle distribution functions appear naturally as power series inX =betahstrok2/2ml2 (beta–1 =kBT,m is the mass,l is a distance related to lattice spacing). These corrections require knowledge of certain particle displacement probabilities in the corresponding classical lattice gases. Leading-order corrections have been derived in forms that should facilitate their use in computer simulation studies of lattice gases by the standard Monte Carlo method.
Keywords:Quantum corrections  lattice gases  equation of state  distribution functions  high-temperature series  Monte Carlo simulation
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