Singlet oxygenation of cycloheptatriene: isolation and characterization of the 1,2-dioxetane |
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| Authors: | Waldemar Adam Hector Rebollo |
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| Affiliation: | Institute of Organic Chemistry, University of Würzburg, Am Hubland, D-8700 Würzburg, West-Germany and Department of Chemistry, University of Puerto Rico, Rio Piedras, Puerto Rico 00931, USA |
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| Abstract: | Tetraphenylporphyrin-sensitized photooxygenation of cycloheptatriene afforded the 1,2-dioxetane () in 9% yield, thus completing the set of possible cycloaddition products; the 1,2-dioxetane () is the precursor to the benzaldehyde product, but not the (2+6)-cycloadduct (). |
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