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Nitroallylation of highly reactive organolithium compounds by 2-nitro-3-pivaloyloxy-1-propene (NPP)
Authors:Paul Knochel  Dieter Seebach
Affiliation:Laboratorium für Organische Chemie der Eidgenössischen Technischen Hochschule, ETH-Zentrum, Universitätstrasse 16, CH-8092 Zürich Switzerland
Abstract:The nitroolefin 1 (NPP) efficiently transfers a 2-nitroallyl group even to the most reactive nucleophilic centres of organolithium reagents to give the products of type 2 listed in the table.
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