Bridged and unbridged norbornyl cations |
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Authors: | Cyril A. Grob Reinhard Hanreich Adrian Waldner |
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Affiliation: | Institute of Organic Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel Switzerland. |
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Abstract: | The solvolysis rates and products of 6-substituted 2-norbornyl-p-toluene-sulfonates and are controlled by 1,3-bridging, i.e. by the degree of bonding between C(6) and C(2) in the intermediate norbornyl cations. |
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