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Bridged and unbridged norbornyl cations
Authors:Cyril A. Grob  Reinhard Hanreich  Adrian Waldner
Affiliation:Institute of Organic Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel Switzerland.
Abstract:The solvolysis rates and products of 6-substituted 2-norbornyl-p-toluene-sulfonates 1 and 5 are controlled by 1,3-bridging, i.e. by the degree of bonding between C(6) and C(2) in the intermediate norbornyl cations.
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