Vibrational spectra and thermodynamic functions of allyl acetate |
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Authors: | Bhadur Singh R Prasad and R M P Jaiswal |
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Institution: | (1) Department of Physics, Kurukshetra University, 132 119 Kurukshetra, India;(2) Department of Chemistry, Regional Engineering College, 132 119 Kurukshetra, India |
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Abstract: | Raman spectrum of allyl acetate molecule has been photographed in liquid phase using 4358 ? line of mercury arc as the exciting
line. Infrared absorption spectrum of the molecule has been recorded in liquid phase in the frequency range 200–4000 cm−1. Both the spectra have been analysed to identify the fundamental frequencies. AssumingC
s
symmetry, the observed fundamental frequencies have been assigned to various modes of vibration and compared with the frequencies
of allyl halides and acetic acid. On the basis of present assignments of fundamental vibrational frequencies and assumed approximate
structural parameters of the molecule, thermodynamic functions have been computed. |
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Keywords: | Vibrational spectra thermodynamic functions allyl acetate |
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