Exploring the reactions of CO2 with PCP supported nickel complexes |
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Authors: | Schmeier Timothy J Hazari Nilay Incarvito Christopher D Raskatov Jevgenij A |
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Affiliation: | The Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520, USA. |
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Abstract: | The reactions of PCP supported Ni hydride, methyl and allyl species with CO(2) to generate Ni carboxylates are described. Computational studies suggest that all three reactions follow different pathways. |
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