On the Oximine Complexes of Transition Metals 106. Spectroscopic and DSC Study of Some Complexes of the Types [Cu(DioxH)2] and [CuX2·DioxH2] |
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| Authors: | Zsakó J. Nagy L. Várhelyi Cs. Novák Cs. Lovász E. |
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| Affiliation: | (1) Faculty of Chemistry, Babes-Bolyai University, Ro-3400 Cluj, Romania;(2) Department of Inorganic and Analytical Chemistry, József Attila University, H-6701 Szeged, P.O. Box, 440, Hungary |
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| Abstract: | Several new complexes of the types [Cu(DioxH)2] and [CuX2·DioxH2] (DioxH2: aliphatic or alicyclic α-dioxime) were obtained and characterized by means of near and far Fourier transformation IR spectroscopy. The thermal decompositions of seven complexes of these types were studied by using DSC measurement data. For several decomposition stages, apparent kinetic parameters were derived by means of the nomogram method. This revised version was published online in July 2006 with corrections to the Cover Date. |
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| Keywords: | copper(II)-oxime complexes DSC kinetic parameters |
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