Synthesis and molecular structure of the complex YbI(bipy)(DME)2 |
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| Authors: | T. V. Petrovskaya I. L. Fedyushkin V. I. Nevodchikov M. N. Bochkarev N. V. Borodina I. L. Eremenko S. E. Nefedov |
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| Affiliation: | (1) G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600 Nizhny Novgorod, Russian Federation;(2) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907 Moscow, Russian Federation |
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| Abstract: | The reaction of the naphthalene complex of ytterbium, [Yb(DME)2]2(μ-C10H8), with 2,2′-bipyridine in 1,2-dimethoxyethane afforded the YbII complex containing the 2,2′-bipyridine radical anion. The resulting complex YbI(bipy)(DME)2 was characterized by IR and ESR spectroscopy, X-ray diffraction analysis, and magnetochemistry. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2341–2344, November, 1998. |
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| Keywords: | ytterbium complexes bipyridine structure |
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