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Zirconium-mediated Selective Synthesis of Quinoline Derivatives |
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| Authors: | MEN Yican ZHANG Jiqian ZHOU Lishan LI Junqiu LIU Jun LI Juan QU Hongmei |
| Affiliation: | 1. Key Laboratory of Systems Bioengineering, Ministry of Education, Tianjin Key Laboratory of Biological and Pharmaceutical Engineering, Department of Pharmaceutical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China; 2. Nantong Dongchang Chemical Industrial Co., Ltd., Nantong 226407, P. R. China; 3. China National Offshore Oil Corp., Tianjin Chemical Research and Design Institute, Tianjin 300131, P. R. China |
| Abstract: | A series of quinoline derivatives was obtained in high yields by an efficient one-pot reaction of substituted o-diiodobenzenes with azazirconacyclopentadienes, which were conveniently prepared from one internal alkyne and one nitrile mediated by zirconocene. This proposed synthetic method provides a feasible way to the synthesis of large N-heterocyclic π-conjugated molecules. |
| Keywords: | Azazirconacyclopentadiene One-pot reaction Quinoline derivative Zirconocene |
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