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Optical properties of Au-core Pt-shell nanorods studied using FDTD simulations
Authors:Jian-Bo Liu  Lin Long  Yu-Shi Zhang  Yue-Ping Wang  Feng-Shou Liu  Wei-Yao Xu  Ming-Ji Zong  Lei Ma  Wen-Qi Liu  Hui Zhang  Jiao Yan  Jia-Qi Chen  Ying-Lu Ji  Xiao-Chun Wu
Affiliation:1. College of Opto-electronic Engineering, Zaozhuang University, Zaozhuang 277100, China2. Zaozhuang Municipal Center for Disease Control and Prevention, Zaozhuang 277100, China3. CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology, Beijing 100190, China
Abstract:Au-core/Pt-shell nanorods (Au@Pt NRs) have been prepared by a Au nanorod-mediated growth method, and they exhibit high electromagnetic field enhancements under coupling conditions. Boosted by a long-range effect of the high electromagnetic field generated by the Au core, the electromagnetic field enhancement can be controlled by changing the morphology of the nanostructures. In this study, we report the results on the simulations of the electromagnetic field enhancement using a finite difference time domain (FDTD) method, taking the real shapes of the Au@Pt NRs into account. Due to the “hot spot” effect, the electromagnetic field can be localized between the Pt nanodots. The electromagnetic field enhancement is found to be rather independent of the Pt content, whereas the local roughness and small sharp features might significantly modify the near-field. As the electromagnetic field enhancement can be tuned by the distribution of Pt nanodots over the Au-core, Au@Pt NRs can find potential applications in related areas.
Keywords:gold  platinum  core-shell  nanorod  FDTD  
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