1, 1'-Binaphthyl-2, 2'-diamine Dihydrochloride: an Efficient Ligand for the N-Arylation of Imidazole with Aryl/heteroaryl Halides Catalyzed by CuI |
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Authors: | SHEN Guodong ZHAO Lingyu BAO Weiliang |
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Affiliation: | 1. School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, P. R. China; 2. Department of Chemistry, Xi Xi Campus, Zhejiang University, Hangzhou 310028, P. R. China |
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Abstract: | Employing 1,1'-binaphthyl-2,2'-diamine(BINAM) dihydrochloride as an efficient and commercially available ligand, relatively mild and highly efficient copper-catalyzed coupling reactions of imidazole with aryl and heteroaryl halides have been developed. Various N-arylimidazoles could be synthesized in moderate to excellent yields. |
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Keywords: | Copper-catalyzed N-arylation N-Arylimidazole Ullmann-type coupling |
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