The redox behavior of 9-nickelafluorenyl sandwich complexes |
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Authors: | Fulvio Rossi Fabrizia Fabrizi de Biani Piero Zanello Piotr Buchalski |
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Institution: | (1) Dipartimento di Chimica, Università di Siena, Via A. De Gasperi, 2, 53100 Siena, Italy;(2) Faculty of Chemistry, Warsaw University of Technology, Koszykowa 75, 00-662 Warsaw, Poland |
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Abstract: | A collection of nickelocene and cobaltocene analogs with one or two nickelafluorenyl rings has been recently synthesized starting
from 9-nickelafluorenyllithium complex. The redox ability of the whole series of derivates has been investigated by electrochemical
techniques, and the nature of the frontier orbitals responsible for the electron transfer activity of this class of compounds
has been supported by extended Hückel calculations.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. |
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Keywords: | Electrochemistry Metallametallocyclic sandwich complexes Extended Hückel calculations |
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