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Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes
Authors:Matioszek Dimitri  Kocsor Tibor-Gabor  Castel Annie  Nemes Gabriela  Escudié Jean  Saffon Nathalie
Affiliation:Université de Toulouse, UPS, LHFA, 118 Route de Narbonne, F-31062 Toulouse, France.
Abstract:The new bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl=PMes*)(2) reacts with L(2)M(CO)(4) (M = Mo, W) to give bidentate complexes with an unexpected coordinating behaviour involving the Ge(II) centre and one phosphorus atom, and with AuI or Me(2)SAuCl to afford the monodentate complexes coordinated at the germanium(II) atom.
Keywords:
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