Phosphaalkenyl germylenes and their gold, tungsten and molybdenum complexes |
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Authors: | Matioszek Dimitri Kocsor Tibor-Gabor Castel Annie Nemes Gabriela Escudié Jean Saffon Nathalie |
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Affiliation: | Université de Toulouse, UPS, LHFA, 118 Route de Narbonne, F-31062 Toulouse, France. |
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Abstract: | The new bis(phosphaalkenyl) germanium(II) compound (NHC)Ge(CCl=PMes*)(2) reacts with L(2)M(CO)(4) (M = Mo, W) to give bidentate complexes with an unexpected coordinating behaviour involving the Ge(II) centre and one phosphorus atom, and with AuI or Me(2)SAuCl to afford the monodentate complexes coordinated at the germanium(II) atom. |
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