Relaxation of strains in fibrillar porous carbon dioxide saturated media near their critical point |
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Authors: | D A Zimnyakov S P Chekmasov O V Ushakova V N Bagratashvili |
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Institution: | 1.Yuri Gagarin State Technical University of Saratov,Saratov,Russia;2.Institute of Laser and Information Technologies,Russian Academy of Sciences,Troitsk (Moscow),Russia |
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Abstract: | The isothermal relaxation of strains in deformed fibrillar porous layers saturated with subcritical or supercritical carbon dioxide has been studied at different temperatures by full-field speckle correlometry. The relaxation of strains is produced by the porous layer—fluid transition of a system from one equilibrium thermodynamic state to another due to a jump-like change in pressure. It has been established that the relaxation time attains a maximum near a critical point and rapidly decreases with increasing deviation of the system temperature from its critical value. The mechanisms of hydrodynamic relaxation in the density of a fluid layer and viscoelastic relaxation in a porous matrix are discussed. It is shown that the experimentally observed slow relaxation of a system is due to the viscoelastic relaxation of a porous fluid saturated layer at equal fluid densities inside and outside the layer. |
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