| 化合物Cs5EuCl8·14H2O和Cs2EuCl5·4H2O的制备和荧光性 |
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| 引用本文： | 董发昕,王 惠,夏树屏. 化合物Cs5EuCl8·14H2O和Cs2EuCl5·4H2O的制备和荧光性[J]. 无机化学学报, 2003, 19(7): 735-738 |
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| 作者姓名： | 董发昕 王 惠 夏树屏 |
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| 作者单位： | 1. 西北大学化学系,西安,710069
2. 化学与材料科学学院,陕西师范大学,西安,710062 |
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| 基金项目： | 国家自然科学基金资助项目(No.29371023)。 |
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| 摘 要： | The two new compounds Cs5EuCl8·14H5O(5∶1 type) and Cs2EuCl5·4H2O(2∶1 type) were found and syn-thesized from CsCl-EuCl3-11%HCl-H2O quaternary systems by phase equilibrium method, and were characterized and measured by ultra-violet absorption spectrometry and fluorescence spectrum. The results show that upconversion spectrum exhibit at 590nm and 610nm exited at 790nm, and the upconversion intensity increases with the EuCl3 ratio increasing in CsCl.
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| 关 键 词： | 相化学平衡与无机合成 Cs5EuCl8·14H2O Cs2EuCl5·4H2O 上转换发光 |
| 修稿时间： | 2003-01-07 |
Study on the Synthesizes and Fluorescence Properties of the Compounds Cs5EuCl8·14H2O and Cs2EuCl5·4H2O |
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| DONG Fa-Xin,WANG Hui and XIA Shu-Ping. Study on the Synthesizes and Fluorescence Properties of the Compounds Cs5EuCl8·14H2O and Cs2EuCl5·4H2O[J]. Chinese Journal of Inorganic Chemistry, 2003, 19(7): 735-738 |
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| Authors: | DONG Fa-Xin WANG Hui XIA Shu-Ping |
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