Intercalation of Toluidines into α-Zirconium Hydrogenphosphate |
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| Authors: | LUDVÍK BENEŠ KLÁRA MELÁNOVÁ JAN SVOBODA VÍTĚZSLAV ZIMA |
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| Affiliation: | (1) Joint Laboratory of Solid State Chemistry of the Institute of Macromolecular Chemistry of Academy of Sciences, University of Pardubice, Studentská 84, 532 10 Pardubice, Czech Republic |
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| Abstract: | Intercalates of o-, m-, and p-toluidine into α-Zr(HPO4)2 · H2O were prepared and characterized by powder X-ray diffraction, thermogravimetric analysis and infrared spectroscopy. As follows from IR, toludine molecules are protonated in the interlayer space. Toluidine molecules are arranged in a bimolecular way in the intercalates containing more than 1.5 toluidine molecules per Zr atom. On the other hand, a monolayer of the toluidine molecules is supposed in the intercalates with less than one toluidine molecule per Zr atom. |
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| Keywords: | α -zirconium hydrogenphosphate intercalation toluidine |
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