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石油磺酸盐体系中相微乳液研究
引用本文:陈咏梅,王涵慧,俞稼镛.石油磺酸盐体系中相微乳液研究[J].物理化学学报,2000,16(8):724-728.
作者姓名:陈咏梅  王涵慧  俞稼镛
作者单位:Institute of Photographic Chemistry,The Chinese Academy of Sciences,Beijing 100101
基金项目:国家攀登(B)计划资助项目
摘    要:宽分子量分布的石油磺酸盐在低浓度时有正丁醇、正构烷烃、盐存在的情况下能成中相微乳液。研究了盐浓度、烷烃种类、醇浓度对该体系中相微乳液的形成及特性影响,得到中相微乳液的特性参数;最佳含盐量S^*、增溶参数σ、盐宽△S、界面张力γ等,并从理论上进行了探讨。采用模拟驱油装置测定了体系的驱油效率,对优化驱油体系设计具有重要意义。

关 键 词:石油磺酸盐  中相微乳液  界面张力  驱油效率  
收稿时间:1999-11-30
修稿时间:1999年11月30

Study of Middle Phase Microemulsion Formed by Petroleum Sulfonate
Chen Yongmei,Wan Hanhui,Yu Jiayong.Study of Middle Phase Microemulsion Formed by Petroleum Sulfonate[J].Acta Physico-Chimica Sinica,2000,16(8):724-728.
Authors:Chen Yongmei  Wan Hanhui  Yu Jiayong
Institution:Institute of Photographic Chemistry,The Chinese Academy of Sciences,Beijing 100101
Abstract:At low concentration (0.4%), in the present of n-butanol, alkanes and brine, petroleum sulfonate (SPS) which has wide range of molecular weight, can form middle phase microemul sion. Using salinity, n-butanol scanning and interfacial tension, we investigated the influence of salinity, n-butanol and kind of alkane on the formation and characteristics of the middle Phase microemulsion of 0.4% SPS/ n-butanol/NaCl/alkane system at V_oil/ V_water=1: 4. Using mimic oil recovery, we investigated the influence of salinity on oil recovery efficiency. It showed in this study that the maximum oil recovery efficiency was connected with optimal salinity and optimal interfacial tension. The results are of particular importance to design slug formation.
Keywords:Petroleum sulfonate  Microemlsion  Interfacial tension  Oilrecovery efficiency
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