Ferroelectric phase transitions in Pb0.96Ba0.04Sc0.5Nb0.5O3 and Pb0.94Ba0.06Sc0.5Nb0.5O3 solid-solution single crystals |
| |
Authors: | L S Kamzina I P Raevskii V V Eremkin V G Smotrakov |
| |
Institution: | (1) Ioffe Physicotechnical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia;(2) Institute of Physics, Rostov State University, Rostov-on-Don, 344090, Russia |
| |
Abstract: | The optical properties of Pb0.96Ba0.04Sc0.5Nb0.5O3 (PBSN-4) and Pb0.94Ba0.06Sc0.5Nb0.5O3 (PBSN-6) single-crystal solid solutions were studied for the first time. It was shown that the spontaneous phase transition occurring in PBSN-4 with no electric field present is accompanied by a sharp minimum in optical transmission, which indicates the percolation nature of the transition. No sharp changes were observed in the temperature dependence of optical transmission in PBSN-6 single crystals with no electric field applied. However, a very weak electric field, ~0.4 kV/cm, is sufficient to induce the ferroelectric state in PBSN-6 single crystals. It was shown that the destruction of the induced ferroelectric state is a first-order phase transition which is accompanied by an anomalously narrow peak in the small-angle light scattering intensity (or by a minimum in optical transmission) and occurs through the percolation mechanism. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|