Neptunium(VI) Chromate Complex with 1,2-Diammoniopropane {H3NCH2CH(NH3)CH3}[(NpO2)2(CrO4)3(H2O)] · 3H2O: Synthesis,Crystal Structure and Properties |
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| Authors: | Budantseva N. A. Andreev G. B. Fedoseev A. M. Antipin M. Yu. |
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| Affiliation: | (1) Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117915, Russia;(2) Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russia |
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| Abstract: | New neptunium(VI) complex {H3NCH2CH(NH3)CH3}[(NpO2)2(CrO4)3(H2O)] · 3H2O is synthesized; its crystal structure is determined and IR and near-IR absorption spectra are recorded. The crystallographic data are: a = 10.805(2) Å, b = 11.238(2) Å, c = 17.615(8) Å, space group P212121, Z = 4, V = 2139(1) Å3, R = 0.051, wR(F2) = 0.109. The crystal structure of the compound is built of the anionic layers of [(NpO2)2(CrO4)3(H2O)]2n–n. The {H3NCH2CH(NH3)CH3}2+ cations and crystallization water molecules are arranged between the layers. Coordination polyhedron of two crystallographically independent Np atoms has the shape of a pentagonal bipyramid. The equatorial plane in one Np polyhedron is formed by the oxygen atoms of four chromate ions and water molecule and by the oxygen atoms of five chromate ions in the other one. |
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