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1D Chain and 3D framework of silver(I) organo-metallic polymers self-assembled with triptycene |
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| Authors: | Ming Wen Megumu Munakata Yi-Zhi Li Yusaku Suenaga Takayoshi Kuroda-Sowa Masahiko Maekawa Manabu Anahata |
| Institution: | 1. Department of Chemistry, Tongji University, 1239# SiPing Road, Shanghai 200092, China;2. Department of Chemistry, Kinki University, Kowakae, Higashi-Osaka, Osaka 577-8502, Japan;3. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China;4. Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka 577-8502, Japan |
| Abstract: | For the purpose of investigating the coordination behavior of sterically congested alkenes and exploring the possibility of non-planar complexation in the polycyclic aromatic system for formation of extended polymeric networks, triptycene (tpty) has been studied with regard to its complexation with the silver(I) ion. The crystal structures of Ag(tpty)(THF)2](ClO4) (1) and Ag6(tpty)4(CF3SO3)2(H2O)6](CF3SO3)4 (2) have been determined by single-crystal X-ray diffraction. The polycyclic aromatic hydrocarbon triptycene is found to offer a potential site for complexation, which can be utilized to generate an interesting array of organo-metallic polymers with one-dimensional (1D) chain and three-dimensional (3D) porous frameworks. |
| Keywords: | Silver(I) complex Triptycene Porous complex |
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