Synthesis,structure and reactivity of novel palladiumdichloride-2,2′-bipyridine with 4,4′-bis(fluorous-ponytail) |
| |
Authors: | Norman Lu Yan-Chou Lin Jeng-Yung Chen Tsung-Chi Chen Shih-Chieh Chen Yuh-Sheng Wen Ling-Kang Liu |
| |
Affiliation: | 1. Institute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei 106, Taiwan;2. Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan |
| |
Abstract: | With the readily available fluorous alkanols RfCH2OH, a series of novel fluorous-ponytailed bpy ligands, 4,4′-bis(RfCH2OCH2)-2,2′-bpy (1a–e), were prepared and treated with [PdCl2(CH3CN)2] to result in the corresponding novel Pd complexes [PdCl2(4,4′-bis(RfCH2OCH2)-2,2′-bpy)] (2a–e) where Rf = n-C3F7 (a), HCF2(CF2)3 (b), HCF2(CF2)7 (c), n-C8F17 (d), n-C10F21 (e). The new ligands and Pd complexes were spectroscopically characterized by multi-nuclei NMR (1H, 19F and 13C), FTIR and high resolution mass (FAB). The structure for the Pd complex 2b, the first with fluorinated ponytails on bpy and not on phosphine, was also established by a single crystal X-ray diffraction study. The TGA data of both ligands and Pd complexes indicated that the Pd-complexes were resistant to higher temperatures than the corresponding ligands. The Pd catalysts derived from 2a–c showed an almost quantitative conversion and could be reused for eight runs with Heck reactions, in that the products and unspent reactants were directly removed by distillation. With the highest fluorine content in the series, Pd complex 2e was successfully applied in the Heck reaction using the fluorous biphasic catalysis strategy. |
| |
Keywords: | Fluorinated palladium complexes Bis(fluorous ponytailed)bipyridine X-ray structure analysis Heck reaction Catalyst recycling Fluorous biphasic catalysis |
本文献已被 ScienceDirect 等数据库收录! |
|