The spin-states and spin-transitions of mononuclear iron(II) complexes of nitrogen-donor ligands |
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Authors: | Malcolm A. Halcrow |
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Affiliation: | School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK |
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Abstract: | A survey of mononuclear iron(II) complexes with heterocyclic N-donor ligation is presented. A brief introduction to spin-crossover chemistry and low-temperature spin-trapping is provided, since many of these compounds undergo thermal spin-transitions upon cooling or heating. These are highlighted, and the structural changes underlying spin-crossover are discussed where this is known. Materials showing spin-trapping behaviour following thermal quenching or irradiation at very low temperatures are also described. |
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Keywords: | N-donor ligands Iron complexes Spin-crossover Magnetic measurements Crystallography |
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