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N-Heterocyclic carbene adducts of cyclopalladated ferrocenylimines: Synthesis,characterization and catalytic activity for the Suzuki–Miyaura reaction
Authors:Jing-Ya Li  A-Juan YuYang-Jie Wu  Yu ZhuChen-Xia Du  Hua-Wei Yang
Institution:Department of Chemistry, Henan key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052, PR China
Abstract:A series of novel air-stable carbene adducts of cyclopalladated ferrocenylimines have been synthesized and characterized. The structures of these complexes were determined by single-crystal X-ray analysis. These adducts have been successfully applied to the Suzuki–Miyaura coupling reaction under aerobic conditions. Good to excellent yields were obtained in short reaction times with a lower loading of the catalyst.
Keywords:Cyclopalladated ferrocenylimines  N-Heterocyclic carbene  Adducts  Crystal structures  Suzuki&ndash  Miyaura coupling reaction  Aryl bromides
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