N-Heterocyclic carbene adducts of cyclopalladated ferrocenylimines: Synthesis,characterization and catalytic activity for the Suzuki–Miyaura reaction |
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Authors: | Jing-Ya Li A-Juan YuYang-Jie Wu Yu ZhuChen-Xia Du Hua-Wei Yang |
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Institution: | Department of Chemistry, Henan key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052, PR China |
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Abstract: | A series of novel air-stable carbene adducts of cyclopalladated ferrocenylimines have been synthesized and characterized. The structures of these complexes were determined by single-crystal X-ray analysis. These adducts have been successfully applied to the Suzuki–Miyaura coupling reaction under aerobic conditions. Good to excellent yields were obtained in short reaction times with a lower loading of the catalyst. |
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Keywords: | Cyclopalladated ferrocenylimines N-Heterocyclic carbene Adducts Crystal structures Suzuki&ndash Miyaura coupling reaction Aryl bromides |
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